Silk

Silk
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This article is about a natural fibre and the textile woven from it. For other uses, see Silk (disambiguation).
Four of the most important domesticated silk worms, together with their adult moth forms, Meyers Konversations-Lexikon (1885-1892)

Silk is a natural protein fibre, some forms of which can be woven into textiles. The best-known type of silk is obtained from the cocoons of the larvae of the mulberry silkworm Bombyx mori reared in captivity (sericulture). The shimmering appearance of silk is due to the triangular prism-like structure of the silk fibre, which allows silk cloth to refract incoming light at different angles, thus producing different colors.

Silks are produced by several other insects, but only the silk of moth caterpillars has been used for textile manufacturing. There has been some research into other silks, which differ at the molecular level. Silks are mainly produced by the larvae of insects that complete metamorphosis, but also by some adult insects such as webspinners. Silk production is especially common in the Hymenoptera (bees, wasps, and ants), and is sometimes used in nest construction. Other types of arthropod produce silk, most notably various arachnids such as spiders (see spider silk).
History
Woven silk textile from tomb no 1. at Mawangdui in Changsha, Hunan province, China, from the Western Han Dynasty, 2nd century BC
Landscape of quick water from high mountain by Zhao Zho, Ming Dynasty, 1611 AD. Hand scroll, ink and colour on silk.
Main article: History of silk
[edit] Wild silk

A variety of wild silks, produced by caterpillars other than the mulberry silkworm have been known and used in China, South Asia, and Europe since ancient times. However, the scale of production was always far smaller than that of cultivated silks. They differ from the domesticated varieties in color and texture, and cocoons gathered in the wild usually have been damaged by the emerging moth before the cocoons are gathered, so the silk thread that makes up the cocoon has been torn into shorter lengths. Commercially reared silkworm pupae are killed by dipping them in boiling water before the adult moths emerge, or by piercing them with a needle, allowing the whole cocoon to be unravelled as one continuous thread. This permits a much stronger cloth to be woven from the silk. Wild silks also tend to be more difficult to dye than silk from the cultivated silkworm
[edit] China

Silk fabric was first developed in ancient China,[1] with some of the earliest examples found as early as 3,500 BC.[2] Legend gives credit for developing silk to a Chinese empress, Lei Zu (Hsi-Ling-Shih, Lei-Tzu). Silks were originally reserved for the Kings of China for their own use and gifts to others, but spread gradually through Chinese culture and trade both geographically and socially, and then to many regions of Asia. Silk rapidly became a popular luxury fabric in the many areas accessible to Chinese merchants because of its texture and luster. Silk was in great demand, and became a staple of pre-industrial international trade. In July 2007, archeologists discovered intricately woven and dyed silk textiles in a tomb in Jiangxi province, dated to the Eastern Zhou Dynasty roughly 2,500 years ago.[3] Although historians have suspected a long history of a formative textile industry in ancient China, this find of silk textiles employing "complicated techniques" of weaving and dyeing provides direct and concrete evidence for silks dating before the Mawangdui-discovery and other silks dating to the Han Dynasty (202 BC-220 AD).[3]

The first evidence of the silk trade is the finding of silk in the hair of an Egyptian mummy of the 21st dynasty, c.1070 BC.[4] Ultimately the silk trade reached as far as the Indian subcontinent, the Middle East, Europe, and North Africa. This trade was so extensive that the major set of trade routes between Europe and Asia has become known as the Silk Road. The highest development was in Japan and China.

The Emperors of China strove to keep knowledge of sericulture secret to maintain the Chinese monopoly. Nonetheless sericulture reached Korea around 200 BC, about the first half of the 1st century AD had reached ancient Khotan,[5] and by AD 300 the practice had been established in India.[citation needed]
Thailand
Main article: Thai silk

Silk is produced, year round, in Thailand by two types of silkworms, the cultured Bombycidae and wild Saturniidae. Most production is after the rice harvest in the southern and northeast parts of the country. Women traditionally weave silk on hand looms, and pass the skill on to their daughters as weaving is considered to be a sign of maturity and eligibility for marriage. Thai silk textiles often use complicated patterns in various colours and styles. Most regions of Thailand have their own typical silks. A single thread filament is too thin to use on its own so women combine many threads to produce a thicker, usable fibre. They do this by hand-reeling the threads onto a wooden spindle to produce a uniform strand of raw silk. The process takes around 40 hours to produce a half kilogram of Thai silk.

Many local operations use a reeling machine for this task, but some silk threads are still hand-reeled. The difference is that hand-reeled threads produce three grades of silk: two fine grades that are ideal for lightweight fabrics, and a thick grade for heavier material.

The silk fabric is soaked in extremely cold water and bleached before dyeing to remove the natural yellow coloring of Thai silk yarn. To do this, skeins of silk thread are immersed in large tubs of hydrogen peroxide. Once washed and dried, the silk is woven on a traditional hand operated loom.[6]
India

Silk, known as "Paat" in Eastern India, Pattu in southern parts of India and Resham in Hindi/Urdu, has a long history in India. Recent archaeological discoveries in Harappa and Chanhu-daro suggest that sericulture, employing wild silk threads from native silkworm species, existed in South Asia during the time of the Indus Valley Civilization, roughly contemporaneous with the earliest known silk use in China.[7] Silk is widely produced today. India is the second largest producer of Silk after China. A majority of the silk in India is produced in Karnataka State, particularly in Mysore and the North Bangalore regions of Muddenahalli, Kanivenarayanapura, and Doddaballapur.[8] India is also the largest consumer of silk in the world. The tradition of wearing silk sarees in marriages by the brides is followed in southern parts of India. Silk is worn by people as a symbol of royalty while attending functions and during festivals. Historically silk was used by the upper classes, while cotton was used by the poorer classes. Today silk is mainly produced in Bhoodhan Pochampally (also known as Silk City), Kanchipuram, Dharmavaram, Mysore, etc. in South India and Banaras in the North for manufacturing garments and sarees. "Murshidabad silk", famous from historical times, is mainly produced in Malda and Murshidabad district of West Bengal and woven with hand looms in Birbhum and Murshidabad district. Another place famous for production of silk is Bhagalpur. The silk from Kanchi is particularly well-known for its classic designs and enduring quality. The silk is traditionally hand-woven and hand-dyed and usually also has silver threads woven into the cloth. Most of this silk is used to make sarees. The sarees usually are very expensive and vibrant in color. Garments made from silk form an integral part of Indian weddings and other celebrations. In the northeastern state of Assam, three different types of silk are produced, collectively called Assam silk: Muga, Eri and Pat silk. Muga, the golden silk, and Eri are produced by silkworms that are native only to Assam. The heritage of silk rearing and weaving is very old and continues today especially with the production of Muga and Pat riha and mekhela chador, the three-piece silk sarees woven with traditional motifs. Mysore Silk Sarees, which are known for their soft texture, last many years if carefully maintained.
Ancient Mediterranean
The Gunthertuch, an 11th-century silk celebrating a Byzantine emperor's triumph

In the Odyssey, 19.233, when Odysseus, while pretending to be someone else, is questioned by Penelope about her husband's clothing, he says that he wore a shirt "gleaming like the skin of a dried onion" (varies with translations, literal translation here)[9] which could refer to the lustrous quality of silk fabric. The Roman Empire knew of and traded in silk. During the reign of emperor Tiberius, sumptuary laws were passed that forbade men from wearing silk garments, but these proved ineffectual.[10] Despite the popularity of silk, the secret of silk-making only reached Europe around AD 550, via the Byzantine Empire. Legend has it that monks working for the emperor Justinian I smuggled silkworm eggs to Constantinople in hollow canes from China. All top-quality looms and weavers were located inside the Palace complex in Constantinople and the cloth produced was used in imperial robes or in diplomacy, as gifts to foreign dignitaries. The remainder was sold at very high prices.
Middle East
Purchasing silkworm cocoons in Antioch, circa 1895.
Dress made from silk

In Islamic teachings, Muslim men are forbidden to wear silk. Many religious jurists believe the reasoning behind the prohibition lies in avoiding clothing for men that can be considered feminine or extravagant.[11] There are disputes regarding the amount of silk a fabric can consist of (i.e., whether a small decorative silk piece on a cotton caftan is permissible or not) for it to be lawful for men to wear but the dominant opinion of most Muslim scholars is that the wearing of silk for men is forbidden.

Despite injunctions against silk for men, silk has retained its popularity in the Islamic world because of its permissibility for women. The Muslim Moors brought silk with them to Spain during their conquest of the Iberian Peninsula.
Medieval and modern Europe

Venetian merchants traded extensively in silk and encouraged silk growers to settle in Italy. By the 13th century, Italian silk was a significant source of trade. Since that period, the silk worked in the province of Como has been the most valuable silk in the world. The wealth of Florence was largely built on textiles, both wool and silk, and other cities like Lucca also grew rich on the trade. Italian silk was so popular in Europe that Francis I of France invited Armenian silk makers to France to create a French silk industry, especially in Lyon. Mass emigration (especially of Huguenots) during periods of religious dispute had seriously damaged French industry and introduced these various textile industries, including silk, to other countries.
Silk clothing in the Tacuinum Sanitatis (XIV century)

James I attempted to establish silk production in England, purchasing and planting 100,000 mulberry trees, some on land adjacent to Hampton Court Palace, but they were of a species unsuited to the silk worms, and the attempt failed. British enterprise also established silk filature in Cyprus in 1928. In England in the mid 20th Century, silk was produced at Lullingstone Castle in Kent. Silkworms were raised and reeled under the direction of Zoe Lady Hart Dyke. Production started elsewhere later. In Italy, the Stazione Bacologica Sperimentale was founded in Padua in 1871 to research sericulture. In the late 19th century, China, Japan, and Italy were the major producers of silk.[citation needed] The most important cities for silk production in Italy were Como and Meldola [12] (Forlì). In medieval times, it was common for silk to be used to make elaborate casings for bananas and other fruits.

Silk was expensive in Medieval Europe and used only by the rich. Italian merchants like Giovanni Arnolfini became hugely wealthy trading it to the Courts of Northern Europe.
North America

James I of England introduced silk-growing to the American colonies around 1619, ostensibly to discourage tobacco planting. The Shakers in Kentucky adopted the practice as did a cottage industry in New England.[13] In the 19th century a new attempt at a silk industry began with European-born workers in Paterson, New Jersey, and the city became a US silk center, although Japanese imports were still more important.

World War II interrupted the silk trade from Japan. Silk prices increased dramatically, and US industry began to look for substitutes, which led to the use of synthetics such as nylon. Synthetic silks have also been made from lyocell, a type of cellulose fiber, and are often difficult to distinguish from real silk (see spider silk for more on synthetic silks).
Properties
Physical properties

Silk fibres from the Bombyx mori silkworm have a triangular cross section with rounded corners, 5-10 μm wide. The fibroin-heavy chain is composed mostly of beta-sheets, due to a 59-mer aminoacid repeat sequence with some variations.[14] The flat surfaces of the fibrils reflect light at many angles, giving silk a natural shine. The cross-section from other silkworms can vary in shape and diameter: crescent-like for Anaphe and elongated wedge for tussah. Silkworm fibres are naturally extruded from two silkworm glands as a pair of primary filaments (brin), which are stuck together, with sericin proteins that act like glue, to form a bave. Bave diameters for tussah silk can reach 65 μm. See cited reference for cross-sectional SEM photographs.[15]

Silk has a smooth, soft texture that is not slippery, unlike many synthetic fibers.

Silk is one of the strongest natural fibres but loses up to 20% of its strength when wet. It has a good moisture regain of 11%. Its elasticity is moderate to poor: if elongated even a small amount, it remains stretched. It can be weakened if exposed to too much sunlight. It may also be attacked by insects, especially if left dirty.

Silk is a poor conductor of electricity and thus susceptible to static cling.

Unwashed silk chiffon may shrink up to 8% due to a relaxation of the fibre macrostructure. So silk should either be pre-washed prior to garment construction, or dry cleaned. Dry cleaning may still shrink the chiffon up to 4%. Occasionally, this shrinkage can be reversed by a gentle steaming with a press cloth. There is almost no gradual shrinkage nor shrinkage due to molecular-level deformation.

Natural and synthetic silk is known to manifest piezoelectric properties in proteins, probably due to its molecular structure.[16]

Silkworm silk was used as the standard for the denier, a measurement of linear density in fibers. Silkworm silk therefore has a linear density of approximately 1 den, or 1.1 dtex.